Using Deposition Rate and Substrate Temperature to Manipulate Liquid Crystal-Like Order in a Vapor-Deposited Hexagonal Columnar Glass

Columnar liquid crystal as a unique ferroelectric liquid crystal

Opening of triangular hole in triangular-shaped chemical vapor deposited hexagonal boron nitride crystal

In-plane heterostructure of monolayer hexagonal boron nitride (h-BN) and graphene is of great interest for its tunable bandgap and other unique properties. Here, we reveal a H2-induced etching process to introduce triangular hole in triangular-shaped chemical vapor deposited individual h-BN crystal. In this study, we synthesized regular triangular-shaped h-BN crystals with the sizes around 2-10...

Transferable single-crystal GaN thin films grown on chemical vapor-deposited hexagonal BN sheets

Single-crystal gallium nitride (GaN) layers were directly grown on centimeter-scale hexagonal boron nitride (h-BN). Using chemical vapor deposition (CVD), centimeter-scale h-BN films were synthesized on a single-crystal Ni(111) and readily transferred onto amorphous fused silica supporting substrates that had no epitaxial relationship with GaN. For growing fully coalescent GaN layers on h-BN, t...

Dynamical heterogeneity in a vapor-deposited polymer glass.

Recently, there has been great interest in "ultrastable" glasses formed via vapor deposition, both because of emerging engineering applications of these materials (e.g., active layers in light-emitting diodes and photovoltaics) and, theoretically, as materials for probing the equilibrium properties of glassy materials below their glass transition, based on the conjecture that these materials ar...

On the rectangular-hexagonal columnar phase transition in disc-like liquid crystals

2014 We report the isobaric binary phase diagram for two disc-like mesogens, hexa-n-octyloxytriphenylene and hexa-n-octanoyloxytriphenylene, which was studied by means of optical texture observations, differential scanning calorimetry and X-ray diffraction measurements. They all confirm the presence of a direct transition between an hexagonal ordered columnar phase and a rectangular disordered ...